On Thursday, the King is launching a distribution centre in south London where charities, including the Felix Project and FareShare, can collect food and take it to help individuals and community groups.
The food comes from places such as supermarkets or the catering industry – and rather than wasting good quality unsold products, it is used to help those facing food poverty.
The King will visit a “surplus-food festival” and meet some of the people who have benefited, with the new hubs intended to increase the food saved.
So far, the Coronation Food Project has rescued 940 tonnes of surplus food, estimated as enough to make 2.24 million meals.
A further 1,900 tonnes has been donated by partners of the project, equivalent to 4.5 million meals.
Three more hubs are due open in the next year, with £15m raised to create a network of up to 10 across the UK.
The King is continuing to be treated for cancer but wants to keep focusing on his work, royal aides have said.
Although he has been on the throne for only two years, he is now the sixth longest-living British monarch.